High-valent iron(IV)–oxo species have been implicated as the key reactive intermediates in
the catalytic cycles of dioxygen activation by heme and non-heme iron enzymes. Our …

The development of cyclometalated Ir(III) complexes has enabled important breakthroughs
in electroluminescence because such complexes permit the efficient population of triplet …

Conspectus Mononuclear nonheme iron enzymes generate high-valent iron(IV)-oxo
intermediates that effect metabolically important oxidative transformations in the catalytic cycle of …

Following the heme paradigm, it is often proposed that dioxygen activation by nonheme
monoiron enzymes involves an iron(IV)=oxo intermediate that is responsible for the substrate …

Nonheme oxoiron(IV) complexes of two pentadentate ligands, N4Py (N,N-bis(2-pyridylmethyl)-bis(2-pyridyl)methylamine)
and Bn-tpen (N-benzyl-N,N‘,N‘-tris(2-pyridylmethyl)-1,2-…

We report the preparation, structural characterization, and detailed lactide polymerization
behavior of a new Zn(II) alkoxide complex, (L 1 ZnOEt) 2 (L 1 = 2,4-di-tert-butyl-6-{[(2‘-…

A new fluorescent sensor based on rhodamine B for Pb 2+ was synthesized. The new
fluorescent sensor showed an extreme selectivity for Pb 2+ over other metal ions examined in …

Background. Blood levels of voriconazole, a first line therapy for invasive aspergillosis, may
correlate with adverse events and treatment response. However, no randomized controlled …

… where w Q is the weight of the quintet reaction in the total … triplet barrier) in proportion to w
Q , which depends on the … will become more important (higher w Q ) and the blended barrier …

… , for efficiency w must be sparse. Local w: We opt to use w’s that correspond to local m×m
blocks of pixels. In other words, we treat x as ah/2 × w/2 × 10 tensor and allow w to operate …